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dx.doi.org/ 10.18577/2307-6046-2020-0-12-3-13

УДК 669.15

Krylov S.А., Makarov А.А., Druzhnov M.A.

Study of high-strength low-alloy steel with super-equilibrium nitrogen content

In continuation of joint work of FSUE «VIAM» and IMET RAN named after Baikov, in the field of obtaining low-alloy steels with increased mechanical properties with a super-equilibrium nitrogen content, the mechanical properties, structure, and chemical composition of the obtained steel were studied. It is shown that steel 10KH3A with a super-equilibrium nitrogen content (up to 0,2) electroslag remelting under pressure DESHP-0,1 (FSUE «VIAM») provides a high level of properties (ultimate strength 1670 MPa) while maintaining high mechanical characteristics (elongation 10%, constriction 50%).

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Reference list

1. Kablov E.N. Innovative development is the most important priority of the state. Metally Evrazii, 2010, no. 2, pp. 6–11.
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13. Blinov V.M., Kostina M.V., Lukin E.I., Blinov E.V., Rigina L.G., Muradyan S.O. Influence of heat treatment on the structure and mechanical properties of low-alloy steel 10Kh3A with a super-equilibrium nitrogen content. Deformatsiya i razrusheniye materialov, 2019, no. 7, pp. 38–41.
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16. Krylov S.A., Evgenov A.G., Makarov A.A., Tonysheva O.A. The ingot PESR. Trudy VIAM, 2017, no. 3, paper no. 03. Available at: http://www.viam-works.ru (accessed: July 21, 2020). DOI: 10.18577/2307-6046-2017-0-3-3-3.
17. Kostina M.V., Rigina L.G., Blinov V.M., Muradyan S.O., Krylov S.A. Technology of obtaining low-alloy martensitic steel 10Kh3A with super-equilibrium nitrogen content. Elektrometallurgiya, 2019, no. 2, pp. 18–26. DOI: 10.31044/1684-5781-2019-0-2-18-26.
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19. Krylov S.A., Shcherbakov A.I., Makarov A.A., Tonysheva O.A. Reduction of non-metallic inclusions in the nitrogen-containing corrosion-resistant steels. Trudy VIAM, 2017, no. 5 (53), paper no. 01. Available at: http://www.viam-works.ru (accessed: June 08, 2020). DOI: 10.18577/2307-6046-2017-0-5-1-1.
20. Shestakov I.I., Voznesenskaya N.M., Tonysheva O.A. Influence of high-temperature thermomechanical treatment on the structure and properties of high-strength corrosion-resistant steel of grade 17H13N4К6SАМ3ch. Trudy VIAM, 2016, no. 6 (42), paper no. 02. Available at: http://viam-works.ru (access: July 13, 2020). DOI: 10.18577/2307-6046-2016-0-6-2-2.
21. Bernstein M.L., Zaimovsky V.A. Structure and mechanical properties of metals. Moscow: Metallurgiya, 1969, 472 p.
22. Bernstein M.L. The structure of deformed metals. Moscow: Metallurgiya, 1977, 431 p.
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dx.doi.org/ 10.18577/2307-6046-2020-0-12-14-22

УДК 669.017.165:669.295

Zavodov A.V., Medvedev P.N., Nochovnaya N.A.

Formation features of adiabatic shear bands during hot compression of VTI-4 alloy and subsequent annealing

Textural and macrostructural changes in the intermetallic titanium alloy VTI-4 based on the orthorhombic phase (Ti₂AlNb) during hot high-rate compression and subsequent recrystallization annealing where studied. The main attention is paid to the formation features of localized deformation bands (LDB) in the central zone of the compressed sample, which are one of the signs of unstable and nonuniform deformation. It is shown that recrystallization annealing after hot compression does not eliminate the LDB and the compression texture. Reasons for this behavior of the material are studied applying the analysis of the solid solution state.

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Reference list

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3. Dzunovich D.A., Alekseyev E.B., Panin P.V., Lukina E.A., Novak A.V. Structure and properties of sheet semi-finished products from various wrought intermetallic titanium alloys. Aviacionnye materialy i tehnologii, 2018, no. 2 (51), pp. 17–25. DOI: 10.18577/2071-9140-2018-0-2-17-25.
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dx.doi.org/ 10.18577/2307-6046-2020-0-12-23-34

УДК 677.53

Farafonov D.P., Serov M.M., Patrushev A.Yu., Leschev N.E., Yaroshenko A.S.

Metal fibers for new aircraft engine materials

Presents the results of work carried out at the Federal state unitary enterprise «VIAM» in the framework of a new material science direction – metallurgy of metal fibers. This work was made possible by the development of a method for producing metal fibers called the hanging melt drop extraction method (EUCR). This method is high-performance and allows you to obtain fibers from almost any material. Research has shown that it is possible to improve the performance and environmental characteristics of modern and advanced engines by introducing new classes of materials based on metal fibers.

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Reference list

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26. Letnikov M.N., Lomberg B.S., Ospennikova O.G., Bakradze M.M. The influence of quench rate on microstructure and mechanical properties of nickel-based wrought superalloy VZh175-ID. Aviacionnye materialy i tehnologii, 2019, No. 2 (55), pp. 21–30. DOI: 10.18577/2071-9140-2019-0-2-21-30.

dx.doi.org/ 10.18577/2307-6046-2020-0-12-35-46

УДК 669.018.292

Panteleev M.D., Sviridov A.V., Skupov A.A., Odintsov N.S.

Perspective welding technologies of aluminum-lithium alloy V-1469 applied to fuselage panels

In this work, we investigated the technological features of promising technologies for laser welding and friction stir welding of high-strength aluminum-lithium alloy V-1469. The modes of laser welding and friction stir welding have been carried out. In this article, we showed the perspective welding methods provide high values of ductility and impact toughness, while the strength of welded joints is not less than 0,8 of the strength of the base material and values of low cycle fatigue is not less than 110·10³ cycles. The results allows to propose laser welding and friction stir welding processes as an alternative to riveted joint for aluminum-lithium alloy V-1469 as applied to the elements of the fuselage.

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Reference list

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19. Serebrennikova N.Yu., Antipov V.V., Senatorova O.G., Erasov V.S., Kashirin V.V. Hybrid multilayer materials based on aluminum-lithium alloys applied to panels of plane wing. Aviacionnye materialy i tehnologii, 2016, no. 3 (42), pp. 3–8. DOI: 10.18577/2071-9140-2016-0-3-3-8.
20. Han B. Double-sided laser beam welded T-joints for aluminum-lithium alloy aircraft fuselage panels: Effects of filler elements on microstructure and mechanical properties. Optics & Laser Technology, 2017, no. 93, pp. 99–108.
21. Antipov V.V., Serebrennikova N.Yu., Shestov V.V., Sidelnikov V.V. Laminated hybrid materials on basis of Al–Li alloy sheets. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 212–224. DOI: 10.18577/2071-9140-2017-0-S-212-224.
22. Hohlatova L.B., Blinkov V.V., Kondratyuk D.I., Ryabova E.N., Kolesenkova O.K. Structure and properties of welded joints of sheets from 1424 and V-1461 alloys made by laser welding. Aviacionnye materialy i tehnologii, 2015, no. 4 (37), pp. 9–13. DOI: 10.18577/2071-9140-2015-0-4-9-13.
23. Shiganov I.N., Kholopov A.A. Laser welding of aluminum alloys. Fotonika, 2010, no. 3, pp. 6–10.
24. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
25. Skupov A.A., Panteleev M.D., Ioda E.N. Microstructure and mechanical properties of V-1579 and V-1481 laser welds. Trudy VIAM, 2017, no. 7 (55), paper no. 7. Available at: http://www.viam-works.ru (accessed: October 14, 2020). DOI: 10.18577/2307-6046-2017-0-7-7-7.
26. Lukin V.I., Ioda E.N., Panteleev M.D., Skupov A.A. Peculiarities of high-strength aluminum-lithium alloys laser welding. Trudy VIAM, 2016, no. 10, paper no. 7. Available at: http://www.viam-works.ru (accessed: October 14, 2020). DOI: 10.18577/2307-6046-2016-0-10-7-7.

dx.doi.org/ 10.18577/2307-6046-2020-0-12-47-58

УДК 678.8

Sidorina A.I., Safronov A.M., Kutsevich K.E., Klimenko O.N.

Carbon fabrics for aircraft products

Current information about the nomenclature of woven reinforcing fillers for composite materials (CM) with a polymer matrix produced at production facilities of FSUE «VIAM», located on the basis of the Voskresensk experimental and technological center for special materials is presented. The main properties of manufactured carbon and hybrid fabrics, promising areas of their application, as well as the main properties of commercially produced and experimental composites based on polymer matrices and woven fillers of FSUE «VIAM» are presented. The directions of further expansion of the range of manufactured woven reinforcing fillers for CM with a polymer matrix are marked.

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Reference list

1. Non-crimp fabric composites: Manufacturing, properties and applications. Ed. S.V. Lomov. Cambridge: Woodhead Publishing, 2011, 544 p.
2. Meola C., Boccardi S., Carlomagno G. Infrared Thermography in the Evaluation of Aerospace Composite Materials. Cambridge: Woodhead Publishing, 2017, 180 p.
3. Kurnosov A.O., Vavilova M.I., Melnikov D.A. Manufacturing technologies of glass fillers and study of effects of finishing material on physical and mechanical properties of fiberglass plastics. Aviacionnye materialy i tehnologii, 2018, no. 1 (50), pp. 64–70. DOI: 10.18577/2071-9140-2018-0-1-64-70.
4. Slavin A.V., Startsev O.V. Properties of aircraft glass- and carbonfibers reinforced plastics at the early stage of natural weathering. Trudy VIAM, 2019, No. 8 (80), paper no. 08. Available at: http://www.viam-works.ru (accessed: October 15, 2020). DOI: 10.18577/2307-6046-2018-0-9-71-82.
5. Timoshkov P.N. Equipment and materials for the technology of automated calculations prepregs. Aviacionnye materialy i tehnologii, 2016, no. 2, pp. 35–39. DOI: 10.18577/2071-9140-2016-0-2-35-39.
6. Hexcel. Available at: http://www.hexcel.com (accessed: October 15, 2020).
7. Porcher industries. Available at: http://www.porcher-ind.com (accessed: October 15, 2020).
8. SGL Carbon. Available at: https://www.sglcarbon.com (accessed: October 15, 2020).
9. Kablov E.N. New generation materials and digital technologies for their processing. Vestnik Rossiyskoy akademii nauk, 2020, vol. 90, no. 4, pp. 331–334.
10. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
11. Sidorina A.I. Mechanical properties of polymer composite materials based on Russian high-strength carbon fillers and new generation polymer matrices. Khimicheskiye volokna, 2018, no. 2, pp. 16–19.
12. Gunyayeva A.G., Sidorina A.I., Kurnosov A.O., Klimenko O.N. Polymeric composite materials of new generation on the basis of binder VSE-1212 and the filling agents alternative to ones of Porcher Ind. and Toho Tenax. Aviacionnye materialy i tehnologii, 2018, no. 3 (52), pp. 18–26. DOI: 10.18577/2071-9140-2018-0-3-18-26.
13. Sidorina A.I., Safronov A.M. Development of carbon fabrics with high surface density manufacturing technologies. Trudy VIAM, 2020, no. 6–7 (89), paper no. 08. Available at: http://www.viam-works.ru (accessed: October 15, 2020). DOI: 10.18577/2307-6046-2020-0-67-72-80.
14. Zhidkova O.G., Kashtanov P.P., Tumanin A.N. Features of the design of composite shaping equipment for the manufacture of high-precision dimensionally stable reflector composite antennas of integral design. Konstruktsii iz kompozitsionnykh materialov, 2019, no. 1, pp. 36–44.
15. Kablov E.N., Gunyaev G.M., Ilchenko S.I. et al. Structural carbon-fiber reinforced plastics with increased conductivity. Aviacionnye materialy i tehnologii, 2004, no. 2, pp. 25–36.

dx.doi.org/ 10.18577/2307-6046-2020-0-12-59-66

УДК 678.747.2

Mishkin S.I., Malakhovskiy S.S., Gunyaeva A.G., Gulyaev I.N.

Features of definition the resin content in carbon fiber reinforced plastics based on various types of carbon fillers by thermo-oxidative destruction method

Research results on definition the mass content of the resin by thermo-oxidative destruction method in constructional CFRP based on the carbon medium-modulus carbon fillers, woven carbon fillers from high-strength fibers and epoxy polymeric matrix are presented. It is shown, which carbon composite materials the thermo-oxidative destruction method is applicable to determine the resin content and possibility application thermo-oxidative method in inert environment is tested. The analysis of the received results is carried out.

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Reference list

1. Kablov E.N. Marketing of materials science, aircraft construction and industry: present and future. Direktor po marketingu i sbytu, 2017, no. 5-6, pp. 40–44.
2. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
3. Kablov E.N., Chursova L.V., Babin A.N., Mukhametov R.R., Panina N.N. Developments of FSUE «VIAM» in the field of melt binders for polymer composite materials. Polimernye materialy i tekhnologii, 2016, vol. 2, no. 2, pp. 37–42.
4. Kablov E.N. New generation materials and digital technologies for their processing. Vestnik Rossiĭskoĭ akademii nauk, 2020, vol. 90, no. 4, pp. 331–334.
5. Grashchenkov D.V. Strategy of development of non-metallic materials, metal composite materials and heat-shielding. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 264–271. DOI: 10.18577/2071-9140-2017-0-S-264-271.
6. Kondrashov S.V., Shashkeev K.A., Petrova G.N., Mekalina I.V. Constructional polymer composites with functional properties. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 405–419. DOI: 10.18577/2071-9140-2017-0-S-405-419.
7. State Standard R 56682–2015. Polymer and metal composites. Methods for determining the volume of the matrix, reinforcing filler and voids. Moscow: Standartinform, 2016, 26 p.
8. ASTM D3171-11. Standart Test Methods for Constituent Content of Composite Materials, 2011, pp. 1–11.
9. State Standard 28006–88. Structural carbon tape. Technical conditions. Moscow: Gosstandart USSR, 1989, 15 p.
10. Ogin S.L., Brondsted P., Zangenberg J. Composite materials: constituents, architecture, and generic damage. Modeling Damage, Fatigue and Failure of Composite Materials, 2016, pp. 3–23. DOI: 10.1016/B978-1-78242-286-0.00001-7.
11. Pavia J., Santos A., Rezende M. Mechanical and morphological characterizations of carbon fiber fabric reinforced epoxy composites used in aeronautical field. Materials Research, 2009, vol. 12, no. 3, pp. 367–374. DOI: 10.1590/S1516-14392009000300019.
12. Zhiqiang H., Sookhyun J., Jackyou N., Daekyum O. Comparative study of glass fiber content measurement methods for inspecting fabrication quality of composite ship structures. Applied Sciences, 2020, no. 10, pp. 1–17. DOI: 10.3390/app10155130.
13. Bondaletova L.I., Bondaletov V.G. Polymer composite materials: textbook. Tomsk: Publ. house of Tomsk. Polytech. Univ., 2013, part 1, 18 p.
14. Dikov I.A., Bojchuk A.S. The review of FRP volume porosity definition with ultrasonic non-destructive technique (review). Trudy VIAM, 2017, no. 2 (50), paper no. 10. Available at: http://viam-works.ru (accessed: September 8, 2020). DOI: 10.18577/2307-6046-2017-0-2-10-10.
15. Babin A. N. Binding for polymeric composite materials of new generation. Trudy VIAM, 2013, no. 4, paper no. 11. Available at: http://www.viam-works.ru (accessed: September 11, 2020).

dx.doi.org/ 10.18577/2307-6046-2020-0-12-67-74

УДК 678.7

Tkachuk A.I., Zagora A.G., Donetskiy K.I., Evdokimov A.A.

Polymeric matrixes for composite materials used in the construction of quickly built bridge structures

The main physico-chemical, thermomechanical and strength characteristics of the epoxy-vinyl-ester polymeric matrixes of the VSV-41 and VSV-43 brands developed at FSUE «VIAM» are considered. It is established that the time of technological viability of these polymeric matrixes in the temperature range of 20–25 °C is 120–130 minutes, which allows them to be processed into products made of polymer composite materials (PCM) of sufficiently large dimensions. Infusion polymeric matrixes of the VSV-41 and VSV-43 brands have similar bending strength indicators, but PCM based on the VSV-43 polymeric matrix have a wider range of operating temperatures. Based on these polymeric matrixes, carbon fiber of the VKU-51 brand, as well as fiberglass of the VPS-58 and VPS-60R brands were developed and certified. In addition, they are used in the manufacture of sheet pilings and supports of arched elements, as well as profiled flooring of structures of a quickly built arch bridge made of composite materials, built in the settlement of Yazykovo in the Ulyanovsk region.

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Reference list

1. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
2. Kablov E.N. New generation materials. Zashchita i bezopasnost, 2014, no. 4, pp. 28–29.
3. Kablov E.N. What to make the future of? New generation materials, technologies for their creation and processing – the basis of innovations. Krylya Rodiny, 2016, no. 5, pp. 8–18.
4. Postnova M.V., Postnov V.I. Development experience out-of-autoclave methods of formation PCM Trudy VIAM, 2014, no. 4, paper no. 06. Available at: http://www.viam-works.ru (accessed: October 5, 2020). DOI 10.18577/2307-6046-2014-0-4-6-6.
5. Panina N.N., Kim M.A., Gurevich Ya.M., Grigoriev M.M., Chursova L.V., Babin A.N. Binders for non-autoclave molding of products from polymer composite materials. Klei. Germetiki. Tekhnologii, 2013, no. 10, pp. 18–27.
6. Kablov E.N., Chursova L.V., Babin A.N., Mukhametov R.R., Panina N.N. Developments of FSUE «VIAM» in the field of melt binders for polymer composite materials. Polimernye materialy i tekhnologii, 2016, vol. 2, no.2, pp. 37–42.
7. Doneckij K.I., Hrulkov A.V. Principles of «green chemistry» in perspective manufacturing technologies of PCM articles. Aviacionnye materialy i tehnologii, 2014, no. S2, pp. 24–28. DOI: 10.18577/2071-9140-2014-0-s2-24-28.
8. Kablov E.N., Chursova L.V., Lukina N.F., Kutsevich K.E., Rubtsova E.V., Petrova A.P. Investigation of epoxy-polysulfone polymer systems as the basis for high-strength adhesives for aviation purposes. Klei. Germetiki. Tekhnologii, 2017, no. 3, pp. 7–12.
9. Vorobiev A. Polyester resins. Components and technologies. 2003, no. 32, pp. 182-185.
10. Dholakiya B. Unsaturated Polyester Resin for Specialty Applications. Polyester. Intech Open, 2012. Chapter 7. P. 400.
11. Gooch J.W. Vinyl Ester Resin. Encyclopedic Dictionary of Polymers. Springer Science Business Media, LLC, 2011, 794 p.
12. Doneckij K.I., Karavaev R.Yu., Raskutin A.E., Panina N.N. Properties of carbon fiber and fiberglass on the basis of braiding preforms. Aviacionnye materialy i tehnologii, 2016, No. 4 (45), pp. 54–59. DOI: 10.18577/2071-9140-2016-0-4-54-59.
13. Donetskiy K.I., Karavayev R.Yu., Tsybin A.I., Veshkin E.A., Mikhaldykin E.S. Constructional fiberglass plastic for manufacturing of enclosing sheeting elements. Aviacionnyye materialy i tehnologii, 2017, no. 3 (48), pp. 56–64. DOI: 10.18577/2071-9140-2017-0-3-56-64.
14. Chursova L.V., Grebeneva T.A., Panina N.N., Tsybin A.I. Binders for polymer composite materials for construction purposes. Vse materialy. Entsiklopedicheskiy spravochnik, 2015, no. 8, pp. 13–17.
15. Murashov V.V., Slyusarev M.V., Evdokimov A.A. Quality control of covers of arch elements of elevated parts of support of fast-erected bridge constructions from PСM. Trudy VIAM, 2016, no. 7, paper no. 10. Available at: http://www.viam-works.ru (accessed: October 5, 2020). DOI: 10.18577/2307-6046-2016-0-7-10-10.
16. Mishkin S.I., Raskutin A.E., Evdokimov A.A., Gulyaev I.N. Technologies and the main stages of construction of the arch bridge first in Russia from composite materials. Trudy VIAM, 2017, no. 6 (54), paper no. 05. Available at: http://www.viam-works.ru (accessed: October 5, 2020). DOI: 10.18577/2307-6046-2017-0-6-5-5.

dx.doi.org/ 10.18577/2307-6046-2020-0-12-75-86

УДК 629.7.023.224

Khmeleva K.M., Kozlov I.A., Nikitin Ya.Yu., Nikiforov A.A.

Modern trends of protective galvanic coatings working at high temperatures (review)

Provides an overview of foreign scientific and technical literature in the field of protective galvanic coatings for heat-resistant alloys based on nickel and γ-TiAl. Various types and systems of alloying of galvanic coatings are considered, which can be used to protect parts of the hot part of gas turbine engines from high-temperature sulfide-oxide corrosion at operating temperatures up to 1000 °С. Data on the influence of the deposition technology, electrolyte composition, additives on the properties of coatings, the morphology of individual coatings, as well as the results of corrosion tests of some coatings are presented.

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Reference list

1. Kablov E.N. The key problem is materials. Trends and guidelines for innovative development in Russia. Moscow: VIAM, 2015.S. 458–464.
2. Volkov A.M., Karashaev M.M., Bakradze M.M., Pustynnikov T.O. Alternative technologies of the incresing of mechanical properties of p/m Ni-based superalloys for jet-engine disk application (review). Trudy VIAM, 2019, No. 8 (80), paper no. 01. Available at: http://www.viam-works.ru (accessed: October 12, 2020). DOI: 10.18577/2307-6046-2019-0-8-3-8.
3. Chabina E.B., Lomberg B.S., Filonova E.V., Ovsepyan S.V., Bakradze M.M. Change of structural and phase condition of heat resisting deformable nickel alloy at alloying tantalum and rhenium. Trudy VIAM, 2015, no. 9, paper no. 03. Available at: http://www.viam-works.ru (accessed: October 12, 2020). DOI: 10.18577/2307-6046-2015-0-9-3-3
4. Chabina E.B. Microalloying influence by lanthanoids on feature of forming of structure grain boundaries and interphase boundaries of / heat resisting nickel alloy of the VZh175 type. Trudy VIAM, 2017, no. 2 (50), paper no. 09. Available at: http://www.viam-works.ru (accessed: October 12, 2020). DOI: 10.18577/2307-6046-2017-0-2-9-9.
5. Razuvaev E.I., Bubnov M.V., Bakradze M.M., Sidorov S.A. HIP and deformation of the granulated heat resisting nickel alloys. Aviacionnye materialy i tehnologii, 2016, no. S1, pp. 80–86. DOI: 10.18577/2071-9140-2016-0-S1-80-86.
6. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
7. Kablov E.N. Modern materials – the basis of innovative modernization of Russia. Metally of Evrazii, 2012, no. 3, pp. 10–15.
8. Kablov E.N. Materials for «Buran» spaceship – innovative solutions of formation of the sixth technological mode. Aviacionnye materialy i tehnologii, 2013, no. S1, pp. 3–9.
9. Khorev A.I. Fundamental and applied projects on titanium alloys and prospective areas of their development as applied to «Buran» spaceship. Aviacionnye materialy i tehnologii, 2013, no. S1, pp. 10–14.
10. Kashapov O.S., Novak A.V., Nochovnaya N.A., Pavlova T.V. Condition, problems and perspectives of creation of heat resisting titanium alloys for GTE details. Trudy VIAM, 2013, no. 3, paper no. 02. Available at: http://www.viam-works.ru (accessed: October 12, 2020).
11. Horev A.I. Fundamental and applied works on structural titanium alloys and perspective directions of their development. Trudy VIAM, 2013, no. 2, paper no. 04. Available at: http://www.viam-works.ru (accessed: October 12, 2020).
12. Kablov E.N. The strategic directions of development of materials and technologies of their processing for the period to 2030. Aviacionnye materialy i tehnologii, 2012, no. S, pp. 7–17.
13. Kablov E.N. VIAM. The direction of the main blow. Nauka i zhizn, 2012., no. 6, pp. 14–18.
14. Antipov V.V. Strategy of development of titanium, magnesium, beryllium and aluminum alloys. Aviacionnye materialy i tehnologii, 2012, no. S, pp. 157–167.
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19. Bouchaud B., Rannou B., Pedraza F. Slurry aluminizing mechanisms of Ni-based superalloys incorporating an electrosynthesized ceria diffusion barrier. Materials Chemistry and Physics, 2013, vol. 143, pp. 416–424.
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23. Bakhit Babak, Akbari Alireza, Nasirpouri Farzad, Ghasem Hosseini Mir. Corrosion resistance of Ni–Co alloy and Ni–Co/SiC nanocompositecoatings electrodeposited by sediment codeposition technique. Applied Surface Science, 2014, vol. 307, pp. 351–359.
24. Pavlatou E.A., Stroumbouli M., Gyftou P., Spyrellis N. Hardening effect induced by incorporation of SiC particles in nickel electrodeposits. Journal of Applied Electrochemistry, 2006, vol. 36, pp. 385–394.
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27. Yue-bo Z., Yuan-zh D. Oxidation resistance of co-deposited Ni–SiC nanocomposite coating. Transactions of Nonferrous Metals Society of China, 2007, vol. 17, pp. 925–928.
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dx.doi.org/ 10.18577/2307-6046-2020-0-12-87-95

УДК 678.026

Kuznetsova V.A., Shapovalov G.G., Marchenko S.A., Kovrizhkina N.A., Silaeva A.A.

Paint coatings on the basis of epoxy and acrylic diphasic polymeric system for coloring of elements of cabin of pilots and dashboards

Influence of the maintenance of filler on adhesion, physicomechanical properties, and also shine of the coverings received on the basis of epoxy and acrylic of film-forming, cured by organic silicon ammine and low-molecular polyamide in initial condition and after artificial aging on the cycle LI-14 (-60D+100) is investigated by °С. Hardness and scratch resistance of systems of coverings on the basis of the developed opaque enamels which in comparison with serial system on the basis of first coat AK-070 and opaque HS-5245 enamel have shown the best results is investigated.

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Reference list

1. Zheleznyak V.G. Modern paint and varnish materials for use in aviation equipment products. Trudy VIAM, 2019, no. 5 (77), paper no. 07. Available at: http://www.viam-works.ru. (accessed: October 17, 2020). DOI: 10.18577/2307-6046-2019-0-5-62-67.
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3. Merkulova Yu.I., Kuznetsova V.A., Novikova T.A. Investigation of properties of coating system based on fluorine polyurethane enamel and primer with low toxical pigment content. Trudy VIAM, 2019, no. 5 (77), paper no. 08. Available at: http://www.viam-works.ru. (accessed: September 16, 2020). DOI: 10.18577/2307-6046-2019-0-5-68-75.
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17. Kablov E.N. The role of chemistry in the creation of new generation materials for complex technical systems. Reports of XX Mendeleev Congress on General and Applied Chemistry. Ekaterinburg: Ural Branch of the Russian Academy of Sciences, 2016, pp. 25–26.
18. Semenova L.V., Malova N.E., Kuznetsova V.A., Pozhoga A.A. Paint and varnish materials and coatings. Aviacionnye materialy i tehnologii, 2012, no. S, pp. 315–327.
19. Kozlova A.A., Kondrashov Je.K. Systems of paint coatings for anticorrosive protection of magnesium alloys. Aviacionnye materialy i tehnologii, 2014, no. 2, pp. 44–47. DOI: 10.18577/2071-9140-2014-0-2-44-47.
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21. Moshinsky L.Ya. Epoxy resins and hardeners (structure, properties, chemistry and topology of curing). Tel Aviv, 1995, 370 p.
22. Kuznetsova V.A., Kuznetsov G.V., Shapovalov G.G. Investigation of epoxy resin molecular mass influence by physiomechanical property and erosive resistant of coatings. Trudy VIAM, 2014, no. 8, paper no. 08. Available at: http://www.viam-works.ru (accessed: November 19, 2020). DOI: 10.18577/2307-6046-2014-0-8-8-8.
23. Kovrizhkina N.A., Kuznetsova V.A., Silaeva A.A., Marchenko S.A. Ways to improve the properties of paint coatings by adding different fillers (review). Aviacionnye materialy i tehnologii, 2019, no. 4 (57), pp. 41–48. DOI: 10.18577/2071-9140-2019-0-4-41-48.
24. Kalinskaya T.V., Drinberg A.S., Itsko E.F. Nanotechnology. Application in the paint and varnish industry. Moscow: LKM-press, 2011, 184 p.
25. Kondrashov E.K., Kuznetsova V.A., Semenova L.V., Lebedeva T.A., Malova N.E. Development of aviation paints and varnishes. Vse materialy. Entsiklopedicheskiy spravochnik, 2012, no. 5, pp. 49–54.

10.

dx.doi.org/ 10.18577/2307-6046-2020-0-12-96-107

УДК 629.7.023.222

Kovrizhkina N.A., Kuznetsova V.A., Silaeva A.A., Emelyanov V.V.

Alternatives to chromate pigments (review)

The review of the researches concerning search of alternative to chromate pigments is provided. Among possible alternatives various connections are considered: cerium salts (in a mix with other non-chromate pigments), compounds of phosphorus, including organic (oxyaminophosphates and oxyethylidenediphosphonates), conductive polymers (polyaniline and polipirrol) and core pigments on their basis, compounds of transitional metals (vanadium, tungsten, molybdenum, manganese, etc.). It is shown that correctly picked up mix of pigments of inhibitive type is capable to provide the level of protective properties which is not conceding to coverings, containing chromate pigments.

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Reference list

1. Kablov E.N. The strategic directions of development of materials and technologies of their processing for the period to 2030. Aviacionnye materialy i tehnologii, 2012, no. S, pp. 7–17.
2. Kablov E.N. Corrosion or life. Nauka i zhizn, 2012, no. 11, pp. 16–21.
3. Zheleznyak V.G. Modern paint and varnish materials for use in aviation equipment products. Trudy VIAM, 2019, no. 5 (77), paper no. 07. Available at: http://www.viam-works.ru. (accessed: October 17, 2020). DOI: 10.18577/2307-6046-2019-0-5-62-67.
4. Twite R.L., Bierwagen G.P. Review of alternatives to chromate for corrosion protection of aluminum aerospace alloys. Progress in Organic Coatings, 1998, no. 33, pp. 91–100.
5. Kablov E.N. Innovative development is the most important priority of the state. Metally Evrazii, 2010, no. 2, pp. 6–11.
6. Merkulova Yu.I., Kuznetsova V.A., Novikova T.A. Investigation of properties of coating system based on fluorine polyurethane enamel and primer with low toxical pigment content. Trudy VIAM, 2019, no. 5 (77), paper no. 08. Available at: http://www.viam-works.ru. (accessed: October 2, 2020). DOI: 10.18577/2307-6046-2019-0-5-68-75.
7. Kablov E.N., Startsev O.V., Medvedev I.M., Shelemba I.S. Fiber optic sensors for monitoring corrosion processes in units of aviation engineering (review). Aviacionnye materialy i tehnologii, 2017, no. 3 (48), pp. 26–34. DOI: 10.18577/2071-9140-2017-0-3-26-34.
8. Kuznetsova V.A., Semenova L.V., Shapovalov G.G. Development trends in the field of anticorrosive polymeric systems for corrosion protection of fixing connections of contact couples of combined structures (review). Aviacionnye materialy i tehnologii, 2017, no. 1 (46), pp. 25–31. DOI: 10.18577/2071-9140-2017-0-1-25-31.
9. Drinberg A.S., Itsko E.F., Kalinskaya T.V. Anti-corrosion primers. Saint Petersburg: NIPROINS LKM and P s OP, 2006, 168 p.
10. Kalininskaya T.V., Drinberg A.S. Colored pigments. Moscow: LKM-press, 2013, 360 p.
11. Chromate-free protective coatings: pat. EP 0792922B1; filed 26.02.97; publ. 03.09.97.
12. Chromate free waterborne epoxy corrosion resistant primer: pat. EP 1433821B1; filed 24.11.03; publ. 30.06.04.
13. Rosenfeld I.L., Rubinstein F.I. Anti-corrosion primers and inhibited paints. Moscow: Khimiya, 1980, 200 p.
14. Anticorrosive pigment: pat. 2330054 Rus. Federation, no. 2007117422/04; filed 04.05.07; publ. 27.07.08.
15. Ashuiko V.A., Ivanova N.P., Salychits O.I. Properties of anticorrosive phosphate-containing pigments for paint and varnish coatings of metals. Energy and material-saving environmentally friendly technologies: abstracts of the X Intern. conf. Grodno, 2013, pp. 117–118.
16. Anticorrosive pigment: pat. 2151157 Rus. Federation, no. 99115751/12; filed 19.07.99; publ. 20.06.00.
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18. Kuznetsova O.S. The use of calcium phosphonate for pigmentation of anticorrosive coatings. Vestnik Kazanskogo tekhnologicheskogo universiteta, 2012, no. 8, pp. 38–39.
19. Sheremetyeva I.M., Vakhin A.V., Svetlakov A.P. Anticorrosive properties of core phosphonate pigments. Vestnik Kazanskogo tekhnologicheskogo universiteta, 2011, no. 11, pp. 142–145.
20. Skorokhodova O.N., Kazakova E.E. New pigments and fillers for the production of paintwork materials. Paint and varnish industry. 2017, no. 6, pp. 20–23.
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25. Kurbatov V.G., Kochkina N.V., Indeikin E.A. The use of shell pigments in the composition of polymeric anticorrosive materials. Uspekhi v khimii i khimicheskoy tekhnologii, 2014, vol. XXVIII, no. 3, pp. 92–96.
26. Sitnov S.A., Vakhin A.V., Khuziakhmetov R.Kh., Stepin S.N. Properties of mechanochemically obtained core phosphonate pigments. Vestnik Kazanskogo tekhnologicheskogo universiteta, 2012, no. 14, pp. 71–73.
27. Anticorrosive pigment: pat. 2237073 Rus. Federation, no. 2003123808/15; filed 29.07.03; publ. 27.09.04.
28. Salychits O.I., Orekhova S.E., Ashuiko V.A. Pigments with anticorrosive properties based on transition metal compounds. Trudy BGT, 2012, no. 3, pp. 16–18.
29. Orekhova S.E., Ashuiko V.A., Kurilo I.I., Salychits O.I. Synthesis and properties of pigments for paints and varnishes with anticorrosive properties. Energy and material-saving environmentally friendly technologies: abstracts of the IX Intern. conf. Grodno, 2011, pp. 42–43.
30. Akulich N.E., Zharsky I.M., Ivanova N.P., Kurilo I.I. Anticorrosive properties of pigments based on bismuth and calcium vanadates. Vesti Natsionalnoy akademii nauk Belarusi, Chemical Science Series, 2016, no. 2, pp. 5–9.
31. Shutova A.L., Globa A.I., Prokopchuk N.R. et al. Features of the use of new pigments in alkyd anticorrosive primers. Trudy BGTU, 2014, no. 4, pp. 43–47.
32. Ziganshina M.R., Stepin S.N. Anticorrosive properties of coatings pigmented with manganese compounds obtained by the ceramic method. Lakokrasochnyye materialy i ikh primeneniye, 2017, no. 3, pp. 34–40.
33. Ziganshina M.R., Stepin S.N., Akhmadieva A.A. et al. Assessment of anticorrosive properties of «manganese blue». Lakokrasochnyye materialy i ikh primeneniye, 2007, no. 9, pp. 19–22.
34. Slobodchikova I.V. Obtaining an epoxy primer using a manganese-containing pigment. Best research work–2017: collection of articles of winners of the VII Int. scientific-practical competition. Penza: Science and Education, 2017, pp. 18–23.
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38. Ziganshina M.R., Vakhin A.V. Physical and mechanical properties of epoxy coatings filled with manganese-containing piments. Vestnik Kazanskogo tekhnologicheskogo universiteta, 2014, no. 5, pp. 42–43.
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42. Gataullina E. D. Anticorrosive properties of calcium phosphate (V) manganate (IV) and the development of primers based on it: thesis abstract, Cand. Sc (Tech.). Kazan: Kazan State Technol. Univ., 2008, 20 p.

11.

dx.doi.org/ 10.18577/2307-6046-2020-0-12-108-115

УДК 620.179

Boychuk A.S., Dikov I.A., Generalov A.S., Yakovleva S.I.

The features of non-destructive inspection of carbon fiber reinforced plastic solid laminate samples during low-cyclic fatigue testing

The results of CFRP samples ultrasonic inspection during low-cyclic fatigue testing are given in this article. It is established that for ultrasonic pulse-echo inspection during cycling mechanical testing and after the special correction of flaw detector’s gain and inspection’s sensitivity concerning back-wall echo decreasing in compare with testing specimen is necessary.

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Reference list

1. Kablov E.N. What to make the future of? New generation materials, technologies for their creation and processing – the basis of innovations. Krylya Rodiny, 2016, no. 5, pp. 8-18.
2. Kablov E.N. VIAM: new generation materials for PD-14. Krylya Rodiny, 2019, no. 7-8, pp. 54–58.
3. Savin S.P. The use of modern polymer composite materials in the design of the airframe of aircraft of the MS-21 family. Izvestiya Samarskogo nauchnogo tsentra RAN, 2012, vol. 14, no. 4 (2), pp. 686–693.
4. Kablov E.N., Chursova L.V., Babin A.N., Mukhametov R.R., Panina N.N. Development of FSUE «VIAM» in the field of melt binders for polymer composite materials. Polimernye materialy i tekhnologii, 2016, vol. 2, no. 2, pp. 37–42.
5. Raskutin A.E. Russian polymer composite materials of new generation, their exploitation and implementation in advanced developed constructions. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 349–367. DOI: 10.18577/2071-9140-2017-0-S-349-367.
6. Kutsevich K.E., Dementeva L.A., Lukina N.F., Tyumeneva T.Yu. Adhesive prepregs as promising materials for parts and assemblies from polymeric composite materials. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 379–387. DOI: 10.18577/2071-9140-2017-0-S-379-387.
7. Kogan D.I., Chursova L.V., Panina N.N. and others. Promising polymeric materials for structural composite products with an energy-efficient molding mode. Plasticheskiye massy, 2020, no. 3–4, pp. 52–54.
8. Mishkin S.I., Raskutin A.E., Evdokimov A.A., Gulyaev I.N. Technologies and the main stages of construction of the arch bridge first in Russia from composite materials. Trudy VIAM, 2017, no. 6 (54), paper no. 05. Available at: http://www.viam-works.ru (accessed: February 1, 2020). DOI: 10.18577/2307-6046-2017-0-6-5-5.
9. Timoshkov P.N. Equipment and materials for the technology of automated calculations prepregs. Aviacionnye materialy i tehnologii, 2016, no. 2, pp. 35–39. DOI: 10.18577/2071-9140-2016-0-2-35-39.
10. Veshkin E.A. Features of out-of-autoclave forming of poor-porous PCM. Trudy VIAM, 2016, no. 2 (38), paper no. 07. Available at: http://www.viam-works.ru (accessed: February 2, 2020). DOI 10.1857/2307-6046-2016-0-2-7-7.
ive testing: a reference book in 8 vols. Ed. V.V. Klyuev. 2nd ed. Moscow: Mashinostroenie, 2006, vol. 3: Ultrasonic control. Eds. I.N. Ermolov, Yu.V. Lange, 864 p.
12. Borisenko V.V. Automation of non-destructive testing of composite materials. V mire nerazrushayushchego kontrolya, 2020, vol. 23, no. 2, pp. 4–7.
13. Boriskov Yu.V. Coherent adaptive focusing for testing composites with complex geometry. V mire nerazrushayushchego kontrolya, 2020, vol. 23, no. 2, pp. 9–12.
14. Bojchuk A.S., Chertishchev V.YU., Dikov I.A., Generalov A.S. Estimation of porosity determination possibility in CFRP by ultrasonic through transmission method. Trudy VIAM, 2017, no. 7 (55), paper no. 11. Available at: http://www.viam-works.ru (accessed: July 28, 2020). DOI: 10.18577/2307-6046-2017-0-7-11-11.
15. Boychuk A.S., Generalov A.S., Dalin M.A., Dikov I.A. Inspection of monolithic parts and structures of aviation equipment made of PCM by ultrasonic non-destructive testing using phased arrays. Proceedings of X All-Russian Conf. TestMat «Main trends, directions and prospects for the development of non-destructive testing methods in the aerospace industry». Moscow: VIAM, 2018, pp. 18–31. Available at: https://conf.viam.ru/sites/default/files/uploads/proceedings/1063.pdf (accessed: August 21, 2020).
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17. Starikovsky G.P., Karabutov A.A., Kuryatin A.A. Nondestructive testing of integral structures made of polymer composite materials. V mire nerazrushayushchego kontrolya, 2011, no. 4, pp. 61–65.
18. Boychuk A.S., Dikov I.A., Generalov A.S. The increase of sensitivity and resolution of FRP solid samples nondestructive ultrasonic testing using the ultrasonic phased array. Aviacionnye materialy i tehnologii, 2019, no. 3 (56), pp. 83–88. DOI: 10.18577 / 2071-9140-2019-0-3-83-88.
19. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
20. Boychuk A.S., Chertishchev V.Yu., Dikov I.A., Generalov A.S., Slavin A.V. Influence of pore morphology on ultrasonic control of porosity in CFRP by the pulse-echo method. Kontrol. Diagnostika, 2018, no. 8, pp. 22–29.

12.

dx.doi.org/ 10.18577/2307-6046-2020-0-12-116-124

УДК 678.84

Beljaev А.А., Bespalova E.E.

Features of measurement of reflective factor in superhigh frequencies by means of analyzers of chains

Features of measurement of factors of reflection of radio absorbing materials by means of analyzers of chains at super-high frequencies are described. Results of measurements of one of standard radio absorbing materials with use of the analyzer of chains are given and comparison with results of measurements by means of a measuring instrument of KSVN panoramic is carried out them. By results of the carried-out measurements conclusions are drawn on possibility of use of the described methods of measurements of factors of reflection of radio absorbing materials.

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Reference list

1. Kablov E.N. Innovative development is the most important priority of the state. Metally Evrazii, 2010, no. 2, pp. 6–11.
2. Kablov E.N. The role of chemistry in the creation of new generation materials for complex technical systems. Reports of XX Mendeleev Congress on General and Applied Chemistry. Ekaterinburg: Ural Branch of the Russian Academy of Sciences, 2016, pp. 25–26.
3. Bogatov V.A., Kondrashov S.V., Hohlov Yu.A. Multifunction optical coatings and materials. Aviacionnye materialy i tehnologii, 2012, no. S, pp. 343–348.
4. Belyaev A.A., Bespalova E.E., Romanov A.M. Fireproof radio absorbing materials for anechoic cameras. Aviacionnye materialy i tehnologii, 2013, no. 1, paper no. 53–55.
5. Agafonova A.S., Belyaev A.A., Kondrashov E.K., Romanov A.M. Features of the formation of monolithic structural radio absorbing materials based on composites filled with resistive fibers. Aviacionnye materialy i tehnologii, 2013, no. 3, pp. 56–59.
6. Doriomedov M.S. Russian and world market of polymer composites (review). Trudy VIAM, 2020, no. 6–7 (89), paper no. 04. Available at: http://www.viam-works.ru (accessed: October 27, 2020). DOI: 10.18577/2307-6046-2020-67-29-37.
7. Brandt L.A. Research of dielectrics at ultrahigh frequencies. Moscow: State. Publ. house phys.-math. lit., 1963, pp. 191–201.
8. Shirokov V.V., Romanov A.M. Waveguide method research of honeycomb glass fibre plastics dielectric characteristics. Aviacionnye materialy i tehnologii, 2013, no. 4, pp. 62–68.
9. Belyaev A.A., Shirokov V.V., Romanov A.M. Investigation of dielectric characteristics of monolithic fiberglass plastics for radio engineering purposes. Kompozitnyy mir, 2014, no. 3 (54), pp. 32–35.
10. Bespalova E.E., Belyaev A.A., Romanov A.M., Shirokov V.V. Investigation of the dielectric characteristics of designed for anechoic chambers laminated radar absorbing material layers based with carbonized fiber filled foam asbestos. Trudy VIAM, 2014, no. 8, paper no. 12. Available at: http://www.viam-works.ru (accessed: October 27, 2020). DOI: 10.18577/2307-6046-2014-0-8-12-12.
11. Lushina M.V., Parshin S.G., Rzhevsky A.A. Modern shielding and radio-absorbing materials. Sistemy upravleniya i obrabotka informatsii, 2011, no. 22, pp. 208–223.
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18. Falkovsky O.I. Technical electrodynamics. Saint Petersburg: Lan, 2009, 244 p.
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20. Nikolsky V.V., Nikolskaya T.I. Electrodynamics and radio wave propagation. Moscow: Librokom, 2012, pp. 44–164.
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