Approaches to the analysis of the adhesive contact area when testing using a modified pull-out method from a «loop-knot».
The contact area was analyzed during the testing of samples using the modified pull-out method from a «knot». The adhesive strength between the domestic carbon fiber UMT42S-3K and the epoxy binder VSE-30 was obtained using the improved pull-out method from a “knot” and the reference pull-out method. The packing density coefficient of the filler in microplastic was investigated using a scanning electron microscope. The strength of carbon monofilaments was determined using a microtensile testing machine.
1. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
2. Rudskoy A.I. Technological heredity in the production and operation of structural materials. Tekhnologiya metallov, 2019, no. 2, pp. 2–10.
3. Tkachuk A.I., Donetsky K.I., Terekhov I.V., Karavaev R.Yu. The use of thermosetting matrices for the manufacture of polymer composite materials by the non-autoclave molding methods. Aviation materials and technology, 2021, no. 1 (62), pp. 22–33. Available at: https://journal.viam.ru (accessed: March 05, 2026). DOI: 10.18577/2713-0193-2021-0-1-22-33.
4. Ogreł L.Yu., Yastrebinskaya A.V., Gorbunova I.Yu. Modification of epoxy binder with polymethylsiloxane for the manufacture of fiberglass pipes and gas exhaust manifolds. Stroitelnye materialy, 2006, no. 5, pp. 57–59.
5. Panina N.N., Grebeneva T.A., Gurevich Ya.M. et al. Modification of epoxy binders with cycloadipatic epoxyimides. Klei. Germetiki. Tekhnologii, 2013, no. 7, pp. 11-17.
6. Yarullin R.R. Modification of epoxy resins as a method for obtaining composite materials with specified physical and mechanical characteristics (review). Plasticheskie massy, 2024, no. 5, pp. 11-17. DOI: 10.35164/0554-2901-2024-05-11-17.
7. Kupriyanova E.V., Morozova T.V., Dvortseva Ya.A.M., Aristov V.M. Modification of an epoxy binder to improve the crack resistance of a composite helmet under impact. Uspekhi v khimii i khimicheskoy tekhnologii, 2019, vol. 33, no. 6 (216), pp. 50-52.
8. Mostovoy A.S., Panova L.G., Kurbatova E.A. Modification of epoxy polymers with a silicon-containing filler to improve performance properties. Voprosy Materialovedeniya, 2016, no. 2 (86), pp. 87-95.
9. Marakhovsky K.M., Osipchik V.S., Vodovozov G.A., Papina S.N. Modification of an epoxy binder with improved characteristics for producing composite materials. Uspekhi v khimii i khimicheskoy tekhnologii, 2016, vol. 30, no. 10 (179), pp. 56-58.
10. Guliev K.G., Ishchenko N.A., Khamedova U.A. et al. Modification of ED-20 epoxy resin with cyclopropane-containing compounds. Plasticheskie massy, 2019, no. 3-4, pp. 19-20.
11. Tretyakov I.V., Vyatkina M.A., Cherevinsky A.P. et al. Effect of polyethersulfone on the properties of epoxy binder and winding fiberglass reinforced plastics based on it. Izvestiya Rossiskyy akademii nauk. Seriya fizicheskaya, 2021, vol. 85, no. 8, pp. 1132-1136. DOI: 10.31857/S0367676521080317.
12. Ivanov A.V., Stolyarov S.O., Dementyev F.A., Ferulev A.P. Study of the performance characteristics of fire-protective coatings based on epoxy resins modified with astralenes. Pozharovzyvobezopasnost, 2020, vol. 29, no. 1, pp. 55-68. DOI: 10.18322/PVB.2020.29.01.55-68.
13. Sidorina A.I. Increasing the adhesion of carbon fiber filler to polymer using finishing (review). Khimicheskie volokna, 2022, no. 5, pp. 3-10.
14. Garifullin A.R., Abdullin I.Sh. Plasma hydrophilization of carbon tape for creating composite materials with enhanced strength characteristics. Vestnik Kazanskogo tekhnologicheskogo universiteta, 2014, vol. 17, no. 14, pp. 101-102.
15. Sagitova F.R., Sharifulin F.S. Modification of carbon fibers and fabrics for their use as reinforcing components in composite materials. Vestnik tekhnologicheskogo universiteta, 2025, vol. 28, no. 8, pp. 81-86. DOI: 10.55421/3034-4689_2025_28_8_81.
16. Andrianova N.N., Borisov A.M., Vorobyova E.A. et al. Modification of the Carbon Fiber Surface by Irradiation with Plasma Ions with Energies from Hundreds of eV to Tens of KeV. Yadernaya fizika i inzhiniring, 2024, vol. 15, no. 3, pp. 224-231. DOI: 10.56304/S2079562923030028.
17. Andrianova N.N., Borisov A.M., Mashkova E.S. et al. Ion-Beam Modification of the Carbon Fiber Surface. Poverkhnost. Rentgenovskie, sinkhotronnye i neytronnye issledovaniya, 2023, no. 4, pp. 10-24. DOI: 10.31857/S1028096023040027.
18. Morozov S.V., Ananyin S.V. The influence of carbon fiber surface modification on the physical and mechanical characteristics of carbon fiber reinforced plastics. Polzunovsky Vestnik, 2022, no. 1, pp. 134-138. DOI: 10.25712/ASTU.2072-8921.2022.01.018.
19. Garifullin A.R. Application of plasma method of modification of carbon fiber surface to improve mechanical properties of carbon fibers. Vestnik tekhnologicheskogo universiteta, 2016, vol. 19, no. 18, pp. 76-77.
20. Moseenkov S.I., Krasnikov D.V., Kazakova M.A. Modification of carbon fiber surface with multiwalled carbon nanotubes and its effect on the mechanical properties of composites with epoxy resin. Zhurnal prikladnoy khimii, 2016, vol. 89, no. 12, pp. 1555-1563.
21. Ivankov R.R. Determination of the strength of the adhesive bond between carbon fibers and an epoxy matrix. Physicomechanical tests, strength and reliability of modern structural and functional materials: Proc. XVII All-Rus. Conf. for testing and research of materials properties «TestMat». Moscow, 2025, pp. 140-162.
22. Gulyayev A.I. Fiber-matrix adhesion strength measurement using nanoindentation (review). Trudy VIAM, 2019, no. 3 (75), pp. 68-78. Available at: http://www.viam-works.ru (accessed: March 05, 2026). DOI: 10.18577/2307-6046-2019-0-3-68-78.
23. Gulyaev A.I., Medvedev P.N., Sbitneva S.V., Petrov A.A. Application of nanoindentation to determine the fiber-matrix adhesion strength in carbon fiber reinforced plastics. The role of fundamental research in the implementation of Strategic directions for the development of materials and technologies for their processing for the period up to 2030: Proc. of the V All-Rus. sci. and tech. conf. Moscow, 2019, pp. 240-253.
24. Ivankov R.R., Sidorina A.I., Kotomin S.V. Determination of the strength of the adhesive bond between Russian carbon fibers and an epoxy matrix using the «loop» pull-out test. Trudy VIAM, 2026, no. 12 (154), pp. 170–184. Available at: http://www.viam-works.ru (accessed: March 05, 2026). DOI: 10.18577/2307-6046-2025-0-12-170-184.
25. Gorbatkina Yu.A. Adhesion strength in polymer-fiber systems. Moscow: Khimiya, 1987, 192 p.
26. Gorbatkina Yu.A., Ivanova-Mumzhieva V.G. Effect of polymer-fiber joint size on change in adhesion strength under various external influences. Part 1. Scale dependence of adhesion strength of fiber-thermosetting binder joints under normal conditions. Klei. Germetiki. Tekhnologii, 2025, no. 9, pp. 25–31. DOI: 10.31044/1813-7008-2025-0-9-25-31.
27. Gorbatkina Yu.A., Ivanova-Mumzhieva V.G. Effect of polymer-fiber joint size on change in adhesion strength under various external influences. Part 2. Effect of the dimensions of thermosetting binder–fiber joints on the temperature dependence of their adhesion strength. Klei. Germetiki. Tekhnologii, 2025, no. 10, pp. 33–37. DOI: 10.31044/1813-7008-2025-0-10-33-37.
28. Vyatkina M.A., Gorbatkina Yu.A., Petrova T.V., Solodilov V.I. Formation of the adhesion strength of epoxy anhydride matrix–fiber systems. Khimicheskaya fizika, 2023, vol. 42, no. 11, pp. 16–22. DOI: 10.31857/S0207401X23110110.
29. Gulyaev A.I., Yerasov V.S., Oreshko E.I., Utkin D.A. Analysis of Carbon Fiber Failure during Multifilament Cylinder Ejection. Klei. Germetiki. Tekhnologii, 2021, no. 1, pp. 28–35. DOI: 10.31044/1813-7008-2021-0-1-28-35.
30. Kotomin S.V., Obidin I.M., Pavlyuchkova E.A. Calculation of the Adhesive Bond Strength of Reinforcing Fibers with Polymers Using the «Loop» Method. Mekhanika kompozitnykh materialov, 2022, vol. 58, no. 1, pp. 197–212.
31. Kotomin S.V., Obidin I.M., Pavlyuchkova E.A. Scale factor in testing adhesive joints of heteroaramid yarns using the «loop» method. Klei. Germetiki. Tekhnologii, 2023, no. 11, pp. 35–40.
32. Kudryavtseva A.N., Tkachuk A.I., Grigorieva K.N., Gurevich Ya.M. The use of epoxy resin system VSE-30, processed by the infusion technology, for the manufacture of low and medium loaded structural polymer composite materials. Trudy VIAM, 2019, no. 1 (73), pp. 31–39. Available at: http://www.viam-works.ru (accessed: March 05, 2026). DOI: 10.18577/2307-6046-2019-0-1-31-39.
33. Gulyaev A.I., Ishodzhanova I.V., Zhuravleva P.L. Application of optical microscopy method for the quantitative analysis of polymer composite material structure. Trudy VIAM, 2014, no. 7, pp. 51–56. Available at: http://viam-works.ru (accessed: March 28, 2026). DOI: 10.18577/2307-6046-2014-0-7-7-7.
34. Nelyub V.A., Guskov A.M., Belov P.A. On the design of carbon fiber-reinforced plastics for tension taking into account fiber adhesion to the matrix. Aktualnye problemy gumanitarnykh i yestestvennykh nauk, 2014, no. 12–1, pp. 62–66.
35. Perepelkin K.E. Reinforcing fibers and fibrous polymer composites. St. Petersburg: Nauchnyye osnovy i tekhnologii, 2009, 184 p.
36. Donetskiy K.I., Karavayev R.Yu., Raskutin A.Ye., Dun V.A. Carbon fibers composite material on the basis of volume reinforcing triax braiding preforms. Trudy VIAM, 2019, no. 1 (73), pp. 55–63. Available at: http://viam-works.ru (accessed: March 28, 2026). DOI: 10.18577/2307-6046-2019-0-1-55-63.
