UDC
544.47:661.898
DOI
10.18577/2307-6046-2026-0-8-108-121
Article PDF (Russian) (1.16 MB)
How to cite
Kirillova V.A., Leonov A.A., Platonova Ya.B., Savilov S.V. Palladium complex compounds as catalysts for cross-coupling reactions for the preparation of functional materials.. Part 2. Suzuki–Miyaura and Mizoroki–Heck reactions // Proceedings of VIAM. 2026. No. 8 (162). С. 108-121. URL: https://www.viam-works.ru. DOI: 10.18577/2307-6046-2026-0-8-108-121.

Palladium complex compounds as catalysts for cross-coupling reactions for the preparation of functional materials.

Part 2. Suzuki–Miyaura and Mizoroki–Heck reactions
Kirillova V.A., Leonov A.A., Platonova Ya.B., Savilov S.V.
Abstract

The review considers catalytic systems based on a variety of palladium complexes for Suzuki–Miyaura and Mizoroki–Heck reactions in homogeneous and heterogeneous versions. It has been shown that the use of organosilenium and carbene ligands makes it possible to achieve quantitative yields at ultra-low catalyst loads. Approaches to the immobilization of complexes onto different carriers that enable repeated use of catalysts and minimal metal loss are considered. The practical significance of the considered reactions for the creation of functional materials with specified characteristics is noted.

Keywords
Suzuki–Miyaura reaction, Mizoroki–Heck reaction, carbene complexes, functional materials, chalcogen-containing ligands, heterogeneous catalysis, immobilization

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