UDC
669.295
DOI
10.18577/2307-6046-2018-0-7-49-57
Article PDF (Russian) (762.91 KB)
How to cite
Panin P.V., Lukinа E.A., Alexeev E.B. Effect of hydrogen doping on structure and phase composition of sheet semi-products of VT23 titanium alloy // Proceedings of VIAM. 2018. No. 7 (67). Ст. 06. URL: https://www.viam-works.ru. DOI: 10.18577/2307-6046-2018-0-7-49-57.

Effect of hydrogen doping on structure and phase composition of sheet semi-products of VT23 titanium alloy

Panin P.V., Lukinа E.A., Alexeev E.B.
Abstract

The influence of extra hydrogen doping on phase and structural transformations in high-strength VT23 alloy has been studied. The volume ratios of α- and β-phases have been defined for room temperature state in dependence on hydrogen amount and hydrogenating annealing temperature in the range from 650 to 800°C. A quantitative estimation of β-phase content and α-particles dimensions in VT23 alloy have been evaluated with hydrogenation parameters being in focus. It has been shown that the alloy contains approximately 30% (vol.) of β-phase in initial condition. Doping with 0,1% (wt.) of hydrogen results in β-phase volume fraction increase from 50% after hydrogenation at 650°C to 80% after hydrogenation at 800°C. The dimensions of α-particles within the mentioned conditions change from 0,6–1,2 to 1,8–2,2 µm.

Keywords
titanium alloy VT23, hydrogen technology, hydrogen doping, hydrogenating annealing, phase composition, structure.
Reference list
  1. Kablov E.N. Iz chego sdelat budushchee? Materialy novogo pokoleniya, tekhnologii ikh sozdaniya i pererabotki – osnova innovatsij [Of what to make the future? Materials of new generation, technology of their creation and processing – basis of innovations] // Krylya Rodiny. 2016. №5. S. 8–18.
  2. Kablov E.N. Materialy novogo pokoleniya – osnova innovatsij, tekhnologicheskogo liderstva i natsionalnoj bezopasnosti Rossii [Materials of new generation – basis of innovations, technological leadership and national security of Russia] // Intellekt i tekhnologii. 2016. №2 (14). S. 16–21.
  3. Kablov E.N. Materialy i khimicheskie tekhnologii dlya aviatsionnoj tekhniki [Materials and chemical technologies for aviation engineering] // Vestnik Rossijskoj akademii nauk. 2012. T. 82. №6. S. 520–530.
  4. Bratukhin A.G. Sovremennye aviatsionnye materialy: tekhnologicheskie i funktsionalnye osobennosti [Modern aviation materials: technological and functional features]. M.: Aviatekhinform, 2003. 440 s.
  5. Vozdvizhenskij V.M., Zhukov A.A., Postnova A.D., Vozdvizhenskaya M.V. Splavy tsvetnykh metallov dlya aviatsionnoj tekhniki [Non-ferrous alloys for aviation engineering]. Rybinsk: RGATA, 2002. 219 s.
  6. Bratukhin A.G., Kolachev B.A., Sadkov V.V. i dr. Tekhnologiya proizvodstva titanovykh samoletnykh konstruktsij [Production technology of titanic aircraft designs]. M.: Mashinostroenie, 1995. 448 s.
  7. Horev A.I. Fundamentalnye i prikladnye raboty po konstrukcionnym titanovym splavam i perspektivnye napravleniya ih razvitiya [Fundamental and applied works on structural titanium alloys and perspective directions of their development] //Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №2. St. 04. Available at: http://www.viam-works.ru (accessed: June 13, 2018).
  8. Ilin A.A., Skvortsova S.V., Spektor V.S., Lukina E.A., Petrov L.M. Nizkotemperaturnoe vakuumnoe ionno-plazmennoe azotirovanie titanovykh splavov raznykh klassov [Low-temperature vacuum ion plasma nitriding of titanium alloys of different classes] // Tekhnologiya legkikh splavov. 2008. №3. S. 103–111.
  9. Lyasotskaya V.S. Termicheskaya obrabotka svarnykh soedinenij titanovykh splavov [Thermal processing of welded compounds of titanium alloys]. M.: Ekomet, 2003. 352 s.
  10. Kollerov M.Yu., Ilin A.A., Filatov A.A., Mamaev V.S. Uprochnyayushchaya termicheskaya obrabotka krupnogabaritnykh polufabrikatov i izdelij iz vysokoprochnykh titanovykh splavov [Strengthening thermal processing of large-size semi-finished products and products from high-strength titanium alloys] // Metallovedenie i termicheskaya obrabotka metallov. 2002. №5. S. 14–17. 11. Kolachev B.A., Polkin I.S., Talalaev V.D. Titanovye splavy raznykh stran [Titanium alloys of the different countries]. M.: VILS, 2000. 318 s.
  11. Novikov I.I. Teoriya termicheskoj obrabotki metallov: uchebnik dlya vuzov. 3-e izd., ispr. i dop. [Theory of thermal processing of metals: the textbook for higher education institutions. 3rd ed., rev. and add.]. M.: Metallurgiya, 1978. 392 s.
  12. Ilin A.A., Kolachev B.A., Nosov V.K., Mamonov A.M. Vodorodnaya tekhnologiya titanovykh splavov / pod obshch. red. A.A. Ilina [Hydrogen technology of titanium alloys / gen. ed. by .A. Ilin]. M: MISiS, 2002. 392 s.
  13. Livanov V.A., Bukhanova A.A., Kolachev B.A. Vodorod v titane [Hydrogen in titanium]. M.: Metallurgiya, 1962. 246 s.
  14. Kolachev B.A. Vodorodnaya khrupkost metallov [Hydrogen embrittlement of metals]. M.: Metallurgiya, 1985. 216 s.
  15. Ilin A.A. Mekhanizm i kinetika fazovykh i strukturnykh prevrashchenij v titanovykh splavakh [The mechanism and kinetics of phase and structural transformations in titanium alloys]. M.: Nauka, 1994. 304 s.
  16. Panin P.V., Manokhin S.S., Dzunovich D.A. Poluchenie i issledovanie submikrokristallicheskoj struktury v titanovykh splavakh pri obratimom legirovanii vodorodom i plasticheskoj deformatsii [Receiving and research of submicrocrystalline structure in titanium alloys at reversible alloying hydrogen and plastic strain] // Voprosy materialovedeniya. 2016. №4 (88). S. 7–17.
  17. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  18. Aviatsionnye materialy: spravochnik v 13 t. 7-e izd., pererab. i dop. / pod obshch. red. E.N. Kablova [Aviation materials: the directory in 13 vol. 7th ed., rev. and add. / gen. ed. by E.N. Kablov]. M.: VIAM, 2010. T. 6: Titanovye splavy. 96 s.
  19. Yakovlev A.L., Filatov A.A., Burkhanova A.A., Popova Yu.A., Nochovnaya N.A Effektivnost primeneniya titanovogo splava VT23 v novykh izdeliyakh «OKB Sukhogo» [Efficiency of application of VT23 titanium alloy in new products of «Sukhoi Design Bureau»] // Titan. 2013. №2 (40). S. 39–42.
  20. Khorev A.I. Kompleksno-legipovannyj titanovyj splav VT23 universalnogo primeneniya [Complex alloyed VT23 titanium alloy of universal application] // Tekhnologiya mashinostpoeniya. 2007. №7. S. 5–11.
  21. Khorev A.I. Titanovyj splav VT23 i ego sravnenie s luchshimi zarubezhnymi splavami [VT23 titanium alloy and its comparison with the best foreign alloys] // Titan. 2006. №1 (18). S. 47–52.
  22. Ilin A.A., Kolachev B.A., Polkin I.S. Titanovye splavy. Sostav, struktura, svojstva: spravochnik [Titanium alloys. Structure, structure, properties: directory]. M.: VILS–MATI, 2009. 520 s.
  23. Protsenko O.M., Karachevtsev F.N., Mekhanik E.A. Opyt razrabotki metodiki izmereniya soderzhaniya vodoroda v titanovyh splavah [Experience on development of measurement procedure for determination of hydrogen content in titanium alloys] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №12. St. 08. Available at: http://www.viam-works.ru (accessed: June 16, 2018). DOI: 10.18577/2307-6046-2014-0-12-8-8.
  24. Kolachev B.A., Betsofen S.Ya., Bunin S.Ya., Volodin V.A. Fiziko-mekhanicheskie svojstva legkikh konstruktsionnykh materialov [Physicomechanical properties of easy constructional materials]. M.: Metallurgiya, 1995. 442 s.
  25. Dzunovich D.A., Panin P.V., Lukina E.A., Shiryaev A.A. Vliyanie rezhimov termicheskoj obrabotki na strukturu i svojstva svarnykh krupnogabaritnykh polufabrikatov iz titanovogo splava VT23 [Heat treatment effect on structure and properties of welded large-dimensioned semi-finished products from VT23 titanium alloy] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2018. №1 (61). St. 07. Available at: http://www.viam-works.ru (accessed: June 13, 2018). DOI: 10.18577/2307-6046-2018-0-1-7-7.
  26. Ilin A.A., Skvortsova S.V., Popova Yu.A., Kudelina I.M. Vliyanie termicheskoj obrabotki na formirovanie struktury i svojstv krupnogabaritnykh polufabrikatov iz splava VT23 [Influence of thermal processing on forming of structure and properties of large-size semi-finished products from alloy VT23] // Titan. 2010. №4. S. 48–53.
  27. Skvortsova S.V., Popova Yu.A., Panin P.V., Grushin I.A., Kuryshev E.A. Vliyanie termicheskoj obrabotki na strukturu i svojstva svarnykh soedinenij iz titanovogo splava VT23 [Influence of thermal processing on structure and property of welded connections from VT23 titanium alloy] // Titan. 2011. №2. S. 16–21.
  28. Panin P.V., Dzunovich D.A., Alekseev E.B. Sposoby opisaniya fazovogo sostava titanovyh splavov, dopolnitelno legirovannyh vodorodom (obzor) [Ways of phase areas representation in titanium alloys additionally doped with hydrogen (review)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №3. St. 03. Available at: http://www.viam-works.ru (accessed: June 13, 2018). DOI: 10.18577/2307-6046-2015-0-3-3-3.
  29. Panin P.V., Shiryaev A.A., Dzunovich D.A. Postroenie temperaturno-kontsentratsionnoj diagrammy fazovogo sostava titanovogo splava VT6, dopolnitelno legirovannogo vodorodom // Tekhnologiya mashinostroeniya. 2014. №3 (141). S. 5–9.
  30. Ilin A.A., Mamonov A.M., Nosov V.K., Majstrov V.M. O vliyanii vodoroda na diffuzionnuyu podvizhnost atomov metallicheskoj podreshetki β-fazy titanovykh splavov [About influence of hydrogen on diffusion mobility of atoms of metal podreshetka β-фазы titanium alloys] // Metally. 1994. №5. S. 99–103.
  31. Ilin A.A., Mikhajlov Yu.V., Nosov V.K., Majstrov V.M. Vliyanie vodoroda na raspredelenie legiruyushchikh elementov mezhdu α- i β-fazami v titanovom splave VT23 [Influence of hydrogen on distribution of doping elements between α-and β-фазами in BT23 titanium alloy] // Fiziko-khimicheskaya mekhanika materialov. 1987. №1. S. 112–114.
  32. Nazimov O.P., Ilin A.A., Kollerov M.Yu. O sostoyanii vodoroda v titane [About condition of hydrogen in titanium] // Zhurnal fizicheskoj khimii. 1980. T. 54. S. 2774–2777.