Salakhova R.K., Tihobrazov A.B., Nazarkin R.M. Obtaining a positive microhardness gradient as a method of increasing the adhesion of electrolytic chromium coatings // Proceedings of VIAM. 2018. No. 3 (63). Ст. 09. URL: https://www.viam-works.ru. DOI: 10.18577/2307-6046-2018-0-3-77-85.

Obtaining a positive microhardness gradient as a method of increasing the adhesion of electrolytic chromium coatings

Salakhova R.K., Tihobrazov A.B., Nazarkin R.M.
Abstract

A method is proposed for obtaining thick chrome coatings in a self-regulating electrolyte with chromium plating with a positive microhardness gradient in thickness. The adhesion strength of the graded chromium coating was estimated by the temperature change method and the impact method on the vertical copra U-2M and metallographic studies of the individual layers of chromium deposited under various electrolysis regimes. The results of the investigation of residual macrostresses by x-ray diffractometric method  in chromium coatings of various microhardness are presented.

Keywords
chrome plating, adhesive strength, microhardness, gradient chromium coating, metallography, coating thickness, residual internal stresses.
Reference list
  1. Dospehi dlya «Burana». Materialy i tehnologii VIAM dlya MKS «Energiya–Buran» / pod red. E.N. Kablova [Armor for «Buran». Materials and VIAM technologies for ISS of «Energiya–Buran» / ed. by E.N. Kablov. 3rd ed.]. M.: Nauka i zhizn, 2013. 128 s.
  2. Kablov E.N. Tendencii i orientiry innovacionnogo razvitiya Rossii: sb. inform. materialov. 3-e izd. [Tendencies and reference points of innovative development of Russia: collection of information materials. 3rd ed.]. M.: VIAM, 2015. 720 s.
  3. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [In-novative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  4. Salahova R.K., Tihoobrazov A.B. Fiziko-himicheskie svojstva oksalatno-sulfatnogo elektrolita hromirovaniya, soderzhashhego nanorazmernye chasticy oksidov metallov [Physical and chemical properties of oxalate-sulfate chromium plating electrolyte, containing metal oxide nanoparticles] // Aviacionnye materialy i tehnologii. 2016. №4 (45). S. 31–39. DOI: 10.18577/2071-9140-2016-0-4-31-39.
  5. Gubarevich G.P., Savchenko A.V., Fomichev V.T. Optimizaciya tehnologicheskih parametrov processa hromirovaniya iz samoreguliruyushhegosya elektrolita s kompleksnoj organo-neorganicheskoj dobavkoj [Optimization of technological parameters of process of chromizing from self-regulating electrolit with complex organo-inorganic additive] // VolgGASU: Internet-vestnik. 2015. Vyp. 4 (40). S. 1–5. URL: http://www.vestnik.vgasu.ru (data obrashheniya: 09.02.2018).
  6. Gubin A.F., Ilin V.I., Kolesnikov V.A. Razrabotka kompleksa specialnyh meropriyatij po povysheniyu himicheskoj bezopasnosti galvanicheskogo proizvodstva [Development of complex of special events for increase of chemical safety of galvanic production] // Himicheskaya i biologicheskaya bezopasnost. 2015. №1–2. S. 83–86.
  7. Vinogradov S.S., Nikiforov A.A., Balahonov S.V. Zamena kadmiya. Etap 1. Povyshenie zashhitnoj sposobnosti cinkovyh pokrytij: termoimmersionnoe i modificirovannoe pokrytiya [Cadmium replacement. Part 1. Improving of protective property of zinc coatings: thermo-immersed and modified coatings] // Aviacionnye materialy i tehnologii. 2015. №4 (37). S. 53–60. DOI: 10.18577/2071-9140-2015-0-4-53-60.
  8. Vinogradov S.S. Ekologicheski bezopasnoe galvanicheskoe proizvodstvo [Ecologically safe galvanic production]. M.: Globus, 1998. Vyp. 3. 298 s.
  9. Lisicyn V.E., Abdulina V.S., Karavaev A.V. i dr. Kriterij ekologichnosti elektroliticheskogo processa hromirovaniya [Criterion of environmental friendliness of electrolytic process of chromizing] // Vestnik TGU. 1999. T. 4. Vyp. 2. S. 240–241.
  10. Ilin V.I., Gubin A.F., Kolesnikov V.A. Minimizaciya obrazovaniya opasnyh himicheskih zhidkih othodov v galvanotehnike (obzor) [Minimization of formation of hazardous chemical liquid waste in galvanotechnics (overview)] // Himiya. Himicheskaya tehnologiya. 2011. №1. S. 29–42.
  11. Molchanov V.F. Effektivnost i kachestvo hromirovaniya detalej [Efficiency and quality of chromizing of details]. Kiev: Tehnika, 1979. 228 s.
  12. Kovenskij I.M., Povetkin V.V. Metallovedenie pokrytij [Metallurgical science of coverings]. M.: Intermet Inzhiniring, 1999. 296 s.
  13. Glyancev N.I., Kotov V.V., Stekolnikov Yu.A. Vliyanie hromirovaniya na fiziko-mehanicheskie svojstva metallov [Influence of chromizing on physicomechanical properties of metals] // Himiya i himicheskaya tehnologiya. 2006. T. 49. Vyp. 9. S. 74–78.
  14. Semenychev V.V., Salahova R.K. Ocenka adgezii nikel-kobaltovogo pokrytiya k steklo- i ugleplastiku metodom carapanya [Evaluation of nickel-cobalt coating adhesion to fiberglass and carbon fiber–reinforced plastic by scratching] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №7 (43). St. 06. Available at: http://www.viam-works.ru (accessed: February 09, 2018). DOI: 10.18577/2307-6046-2016-0-7-6-6.
  15. Pfeiffer W., Koplin C., Reisacher E., Wenzel J. Residual Stresses and Strength of Hard Chromium Coatings // Materials Science Forum. 2011. Vol. 681. Р. 133–138. DOI: 10.4028/www.scientific.net/MSF.681.133.
  16. Solodkova L.N., Kudryavcev V.N. Elektroliticheskoe hromirovanie [Electrolytic chromizing]. M.: Globus, 2007. 191 s.
  17. Truhanov E.M., Kolesnikov A.V., Loshkarev I.D. Dalnodejstvuyushhie napryazheniya v epitaksialnoj plenke, sozdannye dislokaciyami nesootvetstviya [Long-range tension in the epitaxial film, the discrepancies created by dislocations] // Materialy elektronnoj tehniki. 2014. №1 (65). S. 24–31.
  18. Elektrolit dlya hromirovaniya stalej, mednyh i titanovyh splavov: pat. 2187587 Ros. Federaciya [Electrolit for chromizing steel, copper and titanium alloys: pat. 2187587 Rus. Federation]; zayavl. 09.01.01; opubl. 20.08.02, Byul. №23.
  19. Tyurikov E.V., Tihoobrazov A.B., Salahova R.K. Issledovanie svojstv razbavlennogo samoreguliruyushhegosya elektrolita hromirovaniya, soderzhashhego nanorazmernye chas-ticy oksida alyuminiya [Research of properties of the diluted self-regulating chromium plating electrolyte with nano-scale aluminum oxide particles] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №6. St. 06. Available at: http://www.viam-works.ru (accessed: February 09, 2018). DOI: 10.18577/2307-6046-2015-0-6-6-6.
  20. Sposob naneseniya elektroliticheskih pokrytij na osnove hroma: pat. 2457288 Ros. Federaciya [Way of drawing electrolytic coverings on the basis of chrome: pat. 2457288 Russ. Federation]; zayavl. 31.05.11; opubl. 27.07.12, Byul. №21.
  21. Shluger M.A., Tok L.D. Galvanicheskie pokrytiya v mashinostroenii [Galvanic coverings in mechanical engineering]. M.: Mashinostroenie, 1985. T. 2. 248 s.
  22. Bekkert M., Klemm H. Sposoby metallograficheskogo travleniya: spravochnik [Ways of metallographic etching: directory]. M.: Metallurgiya, 1988. 398 s.
  23. Morgunov Yu.A., Saushkin B.P. Additivnye tehnologii dlya aviakosmicheskoj tehniki [The additive technologies for aerospace equipment ] // Additivnye tehnologii. 2016. №1. S. 30–38.
  24. Bogorad L.Ya. Hromirovanie [Chromizing]. L.: Mashinostroenie, 1984. 96 s.