UDC
678.84
DOI
10.18577/2307-6046-2018-0-11-45-53
Article PDF (Russian) (806.59 KB)
How to cite
Prokofiev V.A., Sorokin O.Ju., Vaganova M.L., Lebedeva Yu.E. High-temperature functionally graded material fabricated via reactive alloy infiltration // Proceedings of VIAM. 2018. No. 11 (71). Ст. 06. URL: https://www.viam-works.ru. DOI: 10.18577/2307-6046-2018-0-11-45-53.

High-temperature functionally graded material fabricated via reactive alloy infiltration

Prokofiev V.A., Sorokin O.Ju., Vaganova M.L., Lebedeva Yu.E.
Abstract

Microstructure and properties of HfB2–SiC–B4C–Si ceramics obtained via reactive melt infiltration of SiC–B4C–С porous preform using Si–Hf (8,5% ат.) alloy were studied. It was shown that the ceramics can be defined as a functionally graded material (FGM) in which SiC content increases, whereas HfB2 content decreases from the outer surface to the center. Therefore, HfB2–SiC–B4C ceramics has a rather low density and exhibits high oxidation resistance.

Keywords
high temperature ceramics, infiltration, thermodynamic calculations, Gibb’s energy, eutectic alloy, functionally graded material, oxidation.
Reference list
  1. Kablov E.N. Materialy dlya izdeliya «Buran» – innovacionnye resheniya formirovaniya shestogo tehnologicheskogo uklada [Materials for «Buran» spaceship – innovative solutions of formation of the sixth technological mode] // Aviacionnye materialy i tehnologii. 2013. №S1. S. 3–9.
  2. Kablov E.N., Ospennikova O.G., Vershkov A.V. Redkie metally i redkozemelnye elementy – materialy sovremennyh i budushhih vysokih tehnologij [Rare metals and rare-earth elements are materials for modern and future high technologies] // Aviacionnye materialy i tehnologii. 2013. №S2. S. 3–10.
  3. Kablov E.N., Zhestkov B.E., Grashchenkov D.V., Sorokin O.Yu. et al. Investigation of the oxidative resistance of high-temperature coating based on a SiC material under exposure to high-enthalpy flow // High Temperature. 2017. Vol. 55. No. 6. Р. 857–863.
  4. Kablov E.N., Ospennikova O.G., Svetlov I.L. Vysokoeffektivnoe ohlazhdenie lopatok goryachego trakta GTD [Highly efficient cooling of GTE hot section blades] // Aviacionnye materialy i tehnologii. 2017. №2 (47). S. 3–14. DOI: 10.18577/2071-9140-2017-0-2-3-14.
  5. Simonenko E.P., Sevastyanov D.V., Simonenko N.P., Sevastyanov V.G., Kuznetsov N.T. Promising ultra-high-temperature ceramic materials for aerospace applications // Russian Journal of Inorganic Chemistry. 2013. Vol. 58. No. 14. Р. 1669–1693.
  6. Grashchenkov D.V., Sorokin O.Yu., Lebedeva Yu.E., Vaganova M.L. Specific features of sintering of HfB2-based refractory ceramic by hybrid spark plasma sintering // Russian Journal of Applied Chemistry. 2015. Vol. 88. No. 3. Р. 386–393.
  7. Sakharov K.A., Simonenko E.P., Simonenko N.P., Kablov E.N. et аl. Glycol-citrate synthesis of fine-grained oxides La2-xGdxZrO2O7 and preparation of corresponding ceramics using FAST/SPS process // Ceramics International. 2018. http://doi.org/10.1016/j.ceramint.2018.01.188.
  8. Kablov E.N., Shchetanov B.V., Ivahnenko Yu.A., Balinova Yu.A. Perspektivnye armiruyushhie vysokotemperaturnye volokna dlya metallicheskih i keramicheskih kompozicionnyh materialov [Perspective reinforcing high-temperature fibers for metal and ceramic composite materials] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №2. St. 05. Available at: http://www.viam-works.ru (accessed: April 05, 2018).
  9. Okubo Y., Yano T., Yoshida K. et al. Fabrication of SiC fiber-reinforced SiC matrix composites by low temperature melt infiltration method using Si–Hf and Si–Y alloy // Mechanical Properties and Performance of Engineering Ceramics and Composites IX. 2015. P. 101–111.
  10. Voigt R., Krenkel W., Motz G. Development of ultra-high temperature stable ceramics by reactive infiltration processes // Processing and properties of advanced ceramics and composites III. 2011. P. 123–130.
  11. Aoki T., Ogasawara T., Okubo Y. et. al. Fabrication and properties of Si–Hf alloy melt-infiltrated Tyranno ZMI fiber/SiC-based matrix composites // Composites: Part A. No. 66. 2014. 155–162.
  12. Aoki T., Ogasawara T. ZMI fiber/TiSi2–Si matrix composites for high temperature structural applications // Composites: Part A. 2015. No. 76. P. 102–109.
  13. Kim S., Han I.S., Seong Y.-H., Kim D.K. Mechanical properties of C/SiC composite materials fabricated by the Si–Cr alloy melt-infiltration method // Journal of Composite Materials. 2015. Vol. 49 (24). P. 3057–3066.
  14. Ruggles-Wrenn M., Pope M. Creep behaviour in interlaminar shear of a Hi–NicalonTM/SiC–B4C composite at 1200°C in air and steam // MATEC Web of Conferences. 2015. No. 29. P. 1–13.
  15. Sorokin O.Yu., Grashhenkov D.V., Solntsev S.St., Evdokimov S.A. Keramicheskie kompozicionnye materialy s vysokoj okislitelnoj stojkostyu dlya perspektivnyh letatelnyh apparatov (obzor) [Ceramic composite materials with high oxidation resistance for the novel aircrafts (review)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2014. №6. St. 08. Available at: http://www.viam-works.ru (accessed: October 27, 2018). DOI: 10.18577/2307-6046-2014-0-6-8-8.
  16. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  17. Niihara K.A. Fracture mechanics analysis of indentation-induced Palmqvist crack in ceramics // Journal of Materials Science Letters. 1983. Vol. 2. Р. 221–223.
  18. CERAMTEC. Available at: http://www.ceramtec.com (accessed: June 01, 2018).
  19. 3M Technical Ceramics. Available at: http://www.esk.com. (data obrashcheniya: accessed: June 01, 2018).