Eroshkin S.G., Shvetsova A.N. Development of certified reference materials for titanium and titanium alloy composition // Proceedings of VIAM. 2026. No. 9 (163). С. 184-195. URL: https://www.viam-works.ru. DOI: 10.18577/2307-6046-2026-0-9-184-195.

Development of certified reference materials for titanium and titanium alloy composition

Eroshkin S.G., Shvetsova A.N.
Abstract

Certified reference materials (CRMs) of titanium grades VT1-0 and VT1-00, as well as of titanium alloys VT6, VT6ch, OT4-0, OT4-1, and OT4 have been developed. A batch of CRM material has been manufactured. Homogeneity studies and stability studies of the CRM material have been carried out using the accelerated aging method. The certified values of the CRMs and the relative error of the certified values have been determined. The CRM material has been tested for type approval, and the CRM types have been approved. A test program for serial production of CRMs of titanium and titanium alloys has been developed.

Keywords
certified reference materials, titanium, titanium alloys, spectral analysis, chemical analysis, accelerated aging, optical emission spectrometry



Reference list
  1. Gorynin I.V., Chechulin B.B. Titanium in Mechanical Engineering. Moscow: Mashinostroenie, 1990, 400 p.
  2. Nochovnaya N.A. Prospects and Problems of Application of Titanium Alloys. Prospects for the Development and Application of Titanium Alloys for Aircraft, Rockets, Engines, and Ships: Collection of reports. Moscow, 2007, pp. 5–9.
  3. Trofimov V.V., Fedchishin O.V., Klimenov V.A. Titanium, Titanium Alloys, and Their Application in Dentistry. Sibirskiy meditsinskiy zhurnal, 2009, no. 3, pp. 1–3.
  4. Moiseev V.N., Gribkov Yu.A., Zakharov Yu.I. High-strength titanium alloys in aircraft structures. Prospects for the development and application of titanium alloys for aircraft, rockets, engines and ships: collection of reports. Moscow, 2007, pp. 47–52.
  5. Kolachev B.A., Eliseev Yu.S., Bratukhin A.G., Talalaev V.D. Titanium alloys in the design and production of aircraft engines and aerospace technology. Moscow: MAI Publ. House, 2001, 412 p.
  6. Ushkov S.S., Kudryavtsev A.S. Application of titanium alloys in marine engineering and transport energy and prospects for further development. Prospects for the development and application of titanium alloys for aircraft, rockets, engines and ships: collection of reports. Moscow, 2007, pp. 5–9.
  7. Kollings E.V. Physical Metallurgy of Titanium Alloys. Moscow: Metallurgiya, 1988, 256 p.
  8. Illarionov A.G., Popov A.A. Technological and Operational Properties of Titanium Alloys: A Textbook. Ekaterinburg: Ural Univ. Press, 2014, 137 p.
  9. Putyrskiy S.V., Plokhikh A.I., Arislanov A.A., Naprienko S.A., Anisimova A.Yu. Study of structure and mechanical properties of the laminar structure material based on titanium alloys VT1-0 and VT47. Aviation materials and technologies, 2023, no. 2 (71), pp. 36–50. Available at: http://www.journal.viam.ru (accessed: June 02, 2026). DOI: 10.18577/2713-0193-2023-0-2-36-50.
  10. Ovchinnikov V.V., Slezko M.Yu., Babuev M.A. Magnetron deposition of thin-film coating of the Cu–Mo system on titanium alloy VT6. Aviation materials and technologies, 2025, no. 4 (81), pp. 106–117. Available at: http://www.journal.viam.ru (accessed: June 02, 2026). DOI: 10.18577/2713-0193-2025-0-4-106-117.
  11. Duyunova V.A., Pavlova T.V., Kashapov O.S., Chuchman O.V. Fatigue strength of forgings from VT6 alloy for parts of gas turbine engines and aircrafts. Aviation materials and technologies, 2023, no. 2 (71), pp. 23–35. Available at: http://www.journal.viam.ru (accessed: June 02, 2026). DOI: 10.18577/2713-0193-2023-0-2-23-35.
  12. Duyunova V.A., Oglodkov M.S., Putyrskiy S.V., Kochetkov A.S., Zueva O.V. Modern technologies for melting titanium alloy ingots (review). Aviation materials and technologies, 2022, no. 1 (66), pp. 30–40. Available at: http://www.journal.viam.ru (accessed: June 02, 2026). DOI: 10.18577/2713-0193-2022-0-1-30-40.
  13. Ewing G.W. Instrumental methods of chemical analysis. Moscow: Mir, 1989, 608 p.
  14. Oreshnikova E.G. Spectral analysis. Moscow: Vyshaya shkola, 1982, 375 p.
  15. Otto M. Modern methods of analytical chemistry. 3rd ed. Moscow: Tekhnosfera, 2008, 543 p.
  16. Filichkina V.A., Skorskaya O.L., Muravyova I.V. Methods and means of analytical testing of materials. Chemical and physical-chemical methods of analytical control: textbook. Moscow: Publ. house MISiS, 2015, 107 p.
  17. Stepanovskikh V.V., Kolpakova E.K., Khuzagaleeva R.K. Analytical control of raw materials and products in metallurgy based on the use of certified reference materials. Analitika, 2024, vol. 14, no. 6, pp. 488–491. DOI: 10.22184/2227-572X.2024.14.6.488.491.
  18. Stepanovskikh V.V., Kolpakova E.K., Khuzagaleeva R.K. Analytical testing of ferrous metallurgy materials based on the use of certified standard samples developed by ISO JSC. Standard samples in measurements and technologies: abstract. report VI International scientific conf. Ekaterinburg, 2024, pp. 157–158.
  19. Letov A.F. Application of instrumental methods of analysis to determine the chemical composition of new aviation materials. I All-Rus. conf. on testing and research into the properties of materials «TestMat–2012»: coll. report. Moscow, 2007, pp. 5–9.
  20. Eroshkin S.G., Orlov G.V. Research of material inhomogeneity of reference samples made of wrought Ni-based superalloy VZH175-ID. Trudy VIAM, 2015, no. 8, pp. 83–87. Available at: http://www.viam-works.ru (accessed: June 02, 2026). DOI: 10.18577/2307-6046-2015-0-8-11-11.
  21. Eroshkin S.G., Dynin N.V., Orlov G.V., Petrov P.S. Experience in the development and production of reference materials of composition of aluminum alloy D16. Trudy VIAM, 2017, no. 5 (53), pp. 50–55. Available at: http://www.viam-works.ru (accessed: June 02, 2026). DOI: 10.18577/2307-6046-2017-0-5-6-6.
  22. Stepanovskikh V.V. Metrological traceability of the results of determining the chemical composition of metallurgical materials. Practical issues. Analitika, 2024, vol. 14, no. 2, pp. 184–186. DOI: 10.22184/2227-572X.2024.14.2.184.186.
  23. Kablov E.N., Morozov G.A., Krutikov V.N., Muravskaya N.P. Certification of standard samples of structure of complex-alloyed alloys using standard. Aviacionnye materialy i tehnologii, 2012, no. 2, pp. 9–11.